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C Further elements397

11 Group Ⅲ elements397

11.0 Crystal structure and electronic structure of boron397

11.1 Physical properties of boron399

12 Group Ⅴ elements404

12.0 Crystal structure and electronic structure404

12.1 Phosphorus(P)407

12.2 Arsenic(As)409

12.3 Antimony(Sb)412

12.4 Bismuth(Bi)415

13 Group Ⅵ elements419

13.0 Crystal structure and electronic structure419

13.1 Sulfur(S)422

13.2 Selenium(Se)424

13.3 Tellurium(Te)429

D Further binary compounds434

14 IAx-IBy compounds434

14.0 Crystal structure and electronic structure434

14.1 CsAu434

14.2 RbAu436

15 Ⅰx-Ⅴy compounds437

15.0 Crystal structure and electronic structure437

15.1 Ⅰ-Ⅴ compounds(NaSb,KSb,RbSb,CsSb)440

15.2 Ⅰ3-Ⅴ compounds441

15.2.1 Lattice parameters and melting temperatures441

15.2.2 Li3Sb,Li3Bi442

15.2.3 Na3Sb442

15.2.4 K3Sb442

15.2.5 Rb3Sb443

15.2.6 Cs3Sb443

15.2.7 Rb3Bi,Cs3Bi444

15.3 Ⅰ2-Ⅰ-Ⅴ compounds444

15.3.1 Na2KSb444

15.3.2 K2CsSb444

15.3.3 Na2RbSb,Na2CsSb,K2RbSb,Rb2CsSb445

16 Ⅰx-Ⅵy compounds446

16.0 Crystal structure and electronic structure446

16.1 Cupric oxide(CuO)449

16.2 Cuprous oxide(Cu2O)451

16.3 Copper sulfides(Cu2S,Cu2-xS)454

16.4 Copper selenides(Cu2Se,Cu2 xSe)456

16.5 Copper tellurides(Cu2Te,Cu2-xTe)457

16.6 Silver oxides(AgxOy)458

16.7 Silver sulfide(Ag2S)459

16.8 Silver selenide(Ag2Se)461

16.9 Silver telluride(Ag2Te)462

17 Ⅱx-Ⅳy compounds464

17.0 Crystal structure and electronic structure464

17.1 Magnesium silicide(Mg2Si)465

17.2 Magnesium germanide(Mg2Ge)468

17.3 Magnesium stannide(Mg2Sn)470

17.4 Magnesium plumbide(Mg2Pb)473

17.5 Ca2Si,Ca2Sn,Ca2Pb475

17.6 BaSi2,BaGe2,SrGe2475

18 Ⅱx-Ⅴy compounds476

18.0 Crystal structure and electronic structure476

18.1 Magnesium arsenide(Mg3As2)480

18.2 Zinc phosphide(Zn3P2)481

18.3 Zinc arsenide(Zn3As2)483

18.4 Cadmium phosphide(Cd3P2)485

18.5 Cadmium arsenide(Cd3As2)488

18.6 Zinc phosphide(ZnP2)490

18.7 Zinc arsenide(ZnAs2)493

18.8 Cadmium phosphide(CdP2)495

18.9 Cadmium arsenide(CdAs2)497

18.10 Cadmium tetraphosphide(CdP4)499

18.11 Zinc antimonide(ZnSb)500

18.12 Cadmium antimonide(CdSb)501

18.13 Zinc antimonide(Zn4Sb3)503

18.14 Cadmium antimonide(Cd4Sb3)504

18.15 Cd7P10505

18.16 Cd6P7505

19 Ⅱ-Ⅶ2 compounds507

19.0 Crystal structure and electronic structure507

19.1 Cadmium dichloride(CdCl2)509

19.2 Cadmium dibromide(CdBr2)509

19.3 Cadmium diiodide(CdI2)510

19.4 Mercury diiodide(HgI2)512

20 Ⅲx-Ⅵy compounds515

20.0 Crystal structure and electronic structure515

20.1 Gallium sulfide(GaS)520

20.2 Gallium selenide(GaSe)523

20.3 Gallium telluride(GaTe)527

20.4 Indium sulfide(InS)529

20.5 Indium selenide(InSe)530

20.6 Indium telluride(InTe)533

20.7 Thallium sulfide(TlS)535

20.8 Thallium selenide(TlSe)536

20.9 Thallium telluride(TlTe)538

20.10 In6S7539

20.11 In4Se3540

20.12 In6Se7540

20.13 In6oSe4o541

20.14 In5oSe50542

20.15 In40 Se60542

20.16 In5Se6542

20.17 In4Te3543

20.18 Tl5Te3543

20.19 TlGaS2543

20.20 TlGaSe2545

20.21 TlGaTe2547

20.22 TlInS2548

20.23 TlInSe2550

20.24 TlInTe2551

21 Ⅲ-Ⅶ compounds553

21.0 Crystal structure and electronic structure553

21.1 Thallium fluoride(TlF)555

21.2 Thallium chloride(TlCl)556

21.3 Thallium bromide(TlBr)558

21.4 Thallium iodide(TlI)561

22 Ⅳ-Ⅴ compounds563

22.0 Crystal structure and lattice parameters563

22.1 SiP,GeP564

22.2 SiAs564

22.3 GeAs565

22.4 SiP2,SiAs2565

22.5 GeAs2565

23 Ⅳx-Ⅵy compounds566

23.0 Crystal structure and electronic structure566

23.1 Germanium sulfide(GeS)572

23.2 Germanium selenide(GeSe)574

23.3 Germanium telluride(GeTe)576

23.4 Tin sulfide(SnS)578

23.5 Tin selenide(SnSe)580

23.6 Tin telluride(SnTe)582

23.7 Lead monoxide(PbO)585

23.8 Lead sulfide(PbS)586

23.9 Lead selenide(PbSe)588

23.10 Lead telluride(PbTe)590

23.11 Germanium dioxide(GeO2)593

23.12 Germanium disulfide(GeS2)595

23.13 Germanium diselenide(GeSe2)596

23.14 Tin dioxide(SnO2)597

23.15 Tin disulfide(SnS2)600

23.16 Tin diselenide(SnSe2)602

23.17 Si2Te3603

23.18 Sn2S3,PbSnS3,SnGeS3,PbGeS3605

24 Ⅳ-Ⅶ2 compounds606

24.0 Crystal structure606

24.1 Lead difluoride(PbF2)606

24.2 Lead dichloride(PbCl2)608

24.3 Lead dibromide(PbBr2)609

24.4 Lead diiodide(PbI2)610

25 Ⅴx-Ⅵy compounds613

25.0 Crystal structure and electronic structure613

25.1 Arsenic oxide(As2O3)617

25.1 Arsenic oxide(As2O3)617

25.2 Arsenic sulfide(As2S3)617

25.3 Arsenic selenide(As2Se3)619

25.4 Arsenic telluride(As2Te3)620

25.5 Antimony sulfide(Sb2S3)621

25.6 Antimony selenide(Sb2Se3)622

25.7 Antimony telluride(Sb2Te3)624

25.8 Bismuth oxide(Bi2O3)626

25.9 Bismuth sulfide(Bi2S3)627

25.10 Bismuth selenide(Bi2Se3)628

25.11 Bismuth telluride(Bi2Te3)630

25.12 Realgar(As4S4)633

26 Ⅴ-Ⅶ3 compounds634

26.0 Crystal structure and electronic structure634

26.1 Arsenic triiodide(AsI3)635

26.2 Antimony triiodide(SbI3)636

26.3 Bismuth triiodide(BiI3)637

E Further ternary compounds640

27 Ⅰx-Ⅳy-Ⅵz compounds640

27.0 Crystal structure640

27.1 Ag8GeS6(argyrodite)641

27.2 Ag8SnS6(canfieldite)641

27.3 Ag8SiSe6642

27.4 Ag8GeSe6642

27.5 Ag8SnSe6643

27.6 Ag8GeTe6643

27.7 Cu8GeS6644

27.8 Cu8GeSe6644

27.9 Cu4Ge3S5,Cu4Ge3Se5 and Cu4Sn3Se5644

27.10 Cu4SnS4644

28 Ix-Ⅴy-Ⅵz compounds645

28.0 Crystal structure and electronic structure645

28.1 AgAsS2646

28.2 AgAsSe2646

28.3 AgAsTe2647

28.4 AgSbS2647

28.5 AgSbSe2647

28.6 AgSbTe2648

28.7 AgBiS2648

28.8 AgBiSe2649

28.9 AgBiTe2649

28.10 CuSbSe2650

28.11 CuSbTe2650

28.12 CuBiSe2651

28.13 CuBiTe2651

28.14 Ag3AsS3651

28.15 Ag3SbS3652

29 Ⅱx-Ⅲy-Ⅵz compounds653

29.0 Crystal structure of Ⅱ-Ⅲ-Ⅵ2 compounds653

29.1 CdInS2653

29.2 CdInSe2654

29.3 CdInTe2654

29.4 CdTlS2655

29.5 CdTlSe2655

29.6 CdTlTe2656

29.7 HgTlS2656

30 Ⅲx-Ⅴy-Ⅵz comPounds657

30.0 Crystal structure of Ⅲ-Ⅴ-Ⅵ2 compounds657

30.1 TlAsS2657

30.2 TlSbS2657

30.3 TlBiS2658

30.4 TlBiSe2658

30.5 TlBiTe2659

30.6 Ga6Sb5Te659

30.7 In6Sb5Te659

30.8 In7SbTe6660

31 Ⅳx-Ⅴy-Ⅵz compounds661

31.0 Crystal structure661

31.1 Bi12SiO20661

31.2 Bi12GeO20662

31.3 PbSb2S4,GeSb2Te4,GeBi2Te4,SnBi2Te4662

31.4 GeBi4Te7,GeSb4Te7,PbBi4Te7663

32 Ⅴ-Ⅵ-Ⅶ compounds665

32.0 Crystal structure and electronic structure665

32.1 AsSBr666

32.2 SbSI666

32.3 SbSBr669

32.4 SbSeBr669

32.5 SbSeI669

32.6 SbTeI670

32.7 BiOCl670

32.8 BiOBr670

32.9 BiOI671

32.10 BiSCl671

32.11 BiSBr671

32.12 BiSI671

32.13 BiSeBr672

32.14 BiSeI672

32.15 BiTeBr672

32.16 BiTeI673

33 Further ternary compounds674

33.1 Cu3In5Se9674

33.2 Cu3Ga5Se9674

33.3 Ag3In5Se9675

33.4 Ag3Ga5Se9675

33.5 Cu2Ga4Te7675

33.6 Cu2In4Te7676

33.7 CuIn3Te5676

33.8 AgIn3Te5677

33.9 AgIn5S8677

33.10 AgIn9Te14677

33.11 Cd2SnO4677

33.12 CdSnO3678

33.13 Li3CuO3678

33.14 Hg3PS3,Hg3PS4678

33.15 Cd4(P,As)2(Cl,Br,I)3678

F Boron,transition metal and rare earth compounds with semiconducting properties(data only on the enclosed CD-ROM)679

G Index of substances680

1 Index of substances for chapters 1...33680

2 Index of substances for chapters 34...38685